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Optoelectronic properties of atomically-thin MoS₂flakes are modulated using photochromic diarylethene molecules. The layer-number-dependent charge transfer behaviors at the hybrid heterointerface are elucidated. 

In recommender systems, preference elicitation (PE) is an effective way to learn about a user's preferences to improve recommendation quality. Expected value of information (EVOI), a Bayesian technique that computes expected gain in user utility, has proven to be effective in selecting useful PE queries.Most EVOI methods use probabilistic models of user preferences and query responses to compute posterior utilities.By contrast, we develop model-free variants of EVOI that rely on function approximation to obviate the need for specific modeling assumptions.Specifically, we learn user response and utility models from existing data (often available in real-world recommender systems), which are used to estimate EVOI rather than relying on explicit probabilistic inference.We augment our approach by using online planning, specifically, Monte Carlo tree search, to further enhance our elicitation policies.We show that our approach offers significant improvement in recommendation quality over standard baselines on several PE tasks. 

Abstract The ability to modulate optical and electrical properties of two-dimensional (2D) semiconductors has sparked considerable interest in transition metal dichalcogenides (TMDs). Herein, we introduce a facile strategy for modulating optoelectronic properties of monolayer MoSe₂with external light. Photochromic diarylethene (DAE) molecules formed a 2-nm-thick uniform layer on MoSe₂, switching between its closed- and open-form isomers under UV and visible irradiation, respectively. We have discovered that the closed DAE conformation under UV has its lowest unoccupied molecular orbital energy level lower than the conduction band minimum of MoSe₂, which facilitates photoinduced charge separation at the hybrid interface and quenches photoluminescence (PL) from monolayer flakes. In contrast, open isomers under visible light prevent photoexcited electron transfer from MoSe₂to DAE, thus retaining PL emission properties. Alternating UV and visible light repeatedly show a dynamic modulation of optoelectronic signatures of MoSe₂. Conductive atomic force microscopy and Kelvin probe force microscopy also reveal an increase in conductivity and work function of MoSe₂/DAE with photoswitched closed-form DAE. These results may open new opportunities for designing new phototransistors and other 2D optoelectronic devices. 

Water-stable isotopes in polar ice cores are a widely used temperature proxy in paleoclimate reconstruction, yet calibration remains challenging in East Antarctica. Here, we reconstruct the magnitude and spatial pattern of Last Glacial Maximum surface cooling in Antarctica using borehole thermometry and firn properties in seven ice cores. West Antarctic sites cooled ~10°C relative to the preindustrial period. East Antarctic sites show a range from ~4° to ~7°C cooling, which is consistent with the results of global climate models when the effects of topographic changes indicated with ice core air-content data are included, but less than those indicated with the use of water-stable isotopes calibrated against modern spatial gradients. An altered Antarctic temperature inversion during the glacial reconciles our estimates with water-isotope observations.